JetPack has lot of great functions, one of my favourite is publicize that will auto post published WordPress posts into selected social media like Twitter, Facebook, Google+ etc.
You can modify the content of social post before publishing a post. But if you want to do it automatically, just add the following code somewhere in your plugin or functions.php file.
add_filter( 'wpas_default_message', 'auto_add_publicize_hashtag', 10, 4 );
function auto_add_publicize_hashtag($title) {
$title = $title.' #hashtag1 #hashtag2';
return $title;
}
Once it saved, you publicize screen will be like this:
